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The general difference between PubMed and MEDLINE is that MEDLINE is the curated collection of citations of articles articles published in journals which have been approved by the National Library of Medicine (NLM) and have been indexed by the NLM to have MeSH terms associated with those articles.
PubMed includes MEDLINE, along with other articles which are in the categories of:
For more information see: MEDLINE, PubMed, and PMC (PubMed Central): How are they different?